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Three anthracene derivatives with asymmetric structures, namely 2-phvA, 2-pheA and 2-phA, were synthesised and characterized. Single crystal OFETs of the three compounds were fabricated. 2-pheA and 2-phA showed a mobility of 0.79 cm2 V−1 s−1 and 0.66 cm2 V−1 s−1, while 2-phvA exhibited a high mobility of 10

Crystal structure - Wikipedia

Crystal structure is described in terms of the geometry of arrangement of particles in the unit cell. The unit cell is defined as the smallest repeating unit having the full symmetry of the crystal structure. The geometry of the unit cell is defined as a parallelepiped, providing six lattice parameters taken as the lengths of the cell edges (a, b, c) and the angles between them (α, β, γ ...

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asymmetric crystal - definition - English

The internal vibrations of the SO4-ions at about 1100 cm−1 present a very interesting combination of two solid-state effects on vibrational states of molecules in crystals: a) The threefold degeneracy of this mode is lifted by the deformation of the molecule due to the asymmetric crystal field, and b) the coupling of four molecules in the unit cell (resonance or correlation-field coupling ...

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Symmetry - Wikipedia

Symmetry (from Greek συμμετρία symmetria "agreement in dimensions, due proportion, arrangement") in everyday language refers to a sense of harmonious and beautiful proportion and balance. In mathematics, "symmetry" has a more precise definition, and is usually used to refer to an object that is invariant under some transformations; including translation, reflection, rotation or scaling.

An Investigation of the Yang Photocyclization Reaction in ...

The Norrish/Yang type II photochemistry of 16 ketones having the basic cis-4-tert-butyl-1-benzoylcyclohexane or 2-benzoyladamantane structure has been investigated in the solid state and solution. In both media, ketones bearing methyl substituents α to the benzoyl group undergo stereoselective Yang photocyclization to afford endo-arylcyclobutanols. Quantum yield and quenching studies in ...

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Synthesis, characterization and crystal structure of four ...

Synthesis, characterization and crystal structure of four new asymmetric triazene ligands: An example of linear Hg II complex with Hg ... π secondary bonding interactions. MOHAMMAD REZA MELARDI 1, FATEMEH BABER SHAMSI MOGOII 1, AYOOB BABAII SAJIRANI 1, JAFAR ATTAR GHARAMALEKI 2, BEHROUZ NOTASH 3 & MOHAMMAD KAZEM ROFOUEI 2 Journal of Chemical Sciences volume 127, pages 2171 – 2181 (2015)Cite ...

link.springer.com

Two new branched pentadentate amines (N5), 3,6-bis(2-pyridylmethyl)-5 methyl-3,6-diazaheptane diazahexane-1-amine (1) and 4,7-bis(2-pyridylmethyl)-6-methyl-4,7-diazaheptane-1-amine (2) have been prepared. These have been used for the synthesis for the eight new macroacyclic Schiff base complexes, by template [1 + 1] condensation of pyridine-2-carbaldehyde or O-vaniline and amines (1 and 2) in ...

asymmetrical - LEO: Übersetzung im Englisch ⇔ Deutsch ...

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